Properties of Fluids

Learning Objectives

  • Define a fluid and distinguish the principal mass, weight, viscous, interfacial, and compressibility properties used in hydraulics.
  • Relate density, specific weight, specific volume, and specific gravity using dimensionally consistent equations.
  • Apply Newton's law of viscosity to Newtonian fluids and distinguish dynamic from kinematic viscosity.
  • Explain surface tension through the Young–Laplace pressure jump and apply it to droplets, soap bubbles, liquid jets, and capillary action.
  • Distinguish vapor pressure from gage pressure and identify the absolute-pressure condition associated with cavitation.
  • Use bulk modulus and the ideal-gas equation of state with the correct pressure, temperature, and process assumptions.

Fluid

A fluid is a substance that deforms continuously while subjected to any sustained shear stress. Liquids and gases therefore cannot remain in static equilibrium while a finite shear stress persists.

Why Fluid Properties Matter

Hydraulic analysis repeatedly converts between mass, weight, pressure, shear resistance, interfacial forces, and compressibility. The governing property must match the physical mechanism: density controls mass per volume, specific weight incorporates gravity, viscosity controls viscous shear, surface tension controls interfacial curvature effects, and bulk modulus measures resistance to volumetric compression.

Fluid-property relationshipsMap of density, viscosity, surface effects, and compressibility.densityviscositycompressibility

Fluid-property relationships

Map of density, viscosity, surface effects, and compressibility.

Density, ρ\rho

Density is mass per unit volume at the stated thermodynamic condition.

Density

Relates fluid mass to occupied volume.

ρ=mV\rho = \frac{m}{V}

Variables

SymbolDescriptionUnit
ρ\rhoFluid densitykg/m3kg/m^3
mmFluid masskg
VVFluid volumem3m^3

Specific Weight, γ\gamma

Specific weight is gravitational weight per unit volume at the stated local gravitational acceleration.

Specific Weight

Converts density to weight per unit volume.

γ=ρg\gamma = \rho g

Variables

SymbolDescriptionUnit
γ\gammaFluid specific weightN/m3N/m^3
ρ\rhoFluid densitykg/m3kg/m^3
ggLocal gravitational accelerationm/s2m/s^2

Specific Volume, vv

Specific volume is volume per unit mass and is the reciprocal of density for a homogeneous fluid state.

Specific Volume

Relates occupied volume to fluid mass.

v=Vm=1ρv = \frac{V}{m} = \frac{1}{\rho}

Variables

SymbolDescriptionUnit
vvSpecific volumem3/kgm^3/kg
VVFluid volumem3m^3
mmFluid masskg
ρ\rhoFluid densitykg/m3kg/m^3

Specific Gravity, SGSG

Specific gravity is the dimensionless ratio of a fluid density to a stated reference-fluid density. For liquids in elementary hydraulics, the reference is commonly water at a specified reference temperature.

Specific Gravity of a Liquid

Compares liquid density or specific weight with the corresponding water reference.

SG=ρfluidρwater=γfluidγwaterSG = \frac{\rho_{\text{fluid}}}{\rho_{\text{water}}} = \frac{\gamma_{\text{fluid}}}{\gamma_{\text{water}}}

Variables

SymbolDescriptionUnit
SGSGSpecific gravitydimensionless
ρfluid\rho_{\text{fluid}}Fluid densitykg/m3kg/m^3
ρwater\rho_{\text{water}}Reference-water densitykg/m3kg/m^3
γfluid\gamma_{\text{fluid}}Fluid specific weightN/m3N/m^3
γwater\gamma_{\text{water}}Reference-water specific weightN/m3N/m^3

Reference Values and Temperature Dependence

For many elementary SI calculations, water is approximated as ρ≈1000 kg/m3\rho \approx 1000\ \text{kg/m}^3 and γ≈9.81 kN/m3\gamma \approx 9.81\ \text{kN/m}^3. These are convenient engineering reference values, not universal constants: density and viscosity vary with temperature, pressure, and composition.

Dynamic Viscosity, μ\mu

Dynamic viscosity is the proportionality coefficient relating shear stress to velocity gradient for a Newtonian fluid at a specified thermodynamic state.

Newton's Law of Viscosity

Relates Newtonian shear stress to the local velocity gradient.

τ=μdudy\tau = \mu \frac{du}{dy}

Variables

SymbolDescriptionUnit
τ\tauShear stressPa
μ\muDynamic viscosityPa·s
du/dydu/dyVelocity gradient normal to the flow1/s
Newtonian shear between layersVelocity gradient and tangential shear in a fluid layer.moving platevelocity gradientshear stress

Newtonian shear between layers

Velocity gradient and tangential shear in a fluid layer.

Scope of Newton's Viscosity Law

The linear relation τ=μ du/dy\tau=\mu\,du/dy applies directly to Newtonian fluids. For non-Newtonian fluids, apparent viscosity may depend on shear rate, time, or deformation history, so one constant μ\mu does not describe the full constitutive behavior.

Kinematic Viscosity, ν\nu

Kinematic viscosity is dynamic viscosity divided by density. It has dimensions of momentum diffusivity and does not itself represent a ratio of viscous force to inertial force.

Kinematic Viscosity

Normalizes dynamic viscosity by fluid density.

ν=μρ\nu = \frac{\mu}{\rho}

Variables

SymbolDescriptionUnit
ν\nuKinematic viscositym2/sm^2/s
μ\muDynamic viscosityPa·s
ρ\rhoFluid densitykg/m3kg/m^3

Common Viscosity Units

1 P=0.1 Pa⋅s1\ \text{P}=0.1\ \text{Pa·s}, 1 cP=10−3 Pa⋅s1\ \text{cP}=10^{-3}\ \text{Pa·s}, 1 St=10−4 m2/s1\ \text{St}=10^{-4}\ \text{m}^2/\text{s}, and 1 cSt=10−6 m2/s1\ \text{cSt}=10^{-6}\ \text{m}^2/\text{s}. For liquids such as water, viscosity generally decreases as temperature rises over ordinary engineering ranges.

Interactive Fluid-Property Exploration

Use the simulation to compare how changes in fluid type and properties affect viscous and interfacial behavior. Treat displayed property values as model inputs and keep temperature dependence in mind when applying tabulated data.

Fluid Properties Explorer

Learning objective: Connect representative fluid properties to viscous shear, capillary response, and model-validity limits without treating illustrative material values as universal constants.

Representative properties near 20°C. Actual values vary with temperature, composition, and surface condition. Contact angle is an explicit modeling assumption for the glass-liquid pair.

NIST-consistent reference values near 20 °C

Idealized equilibrium capillary rise

Assumed contact angle, θ\theta
0°
Capillary length, ℓc\ell_c
2.73 mm
Bond number, Bo=(r/ℓc)2Bo=(r/\ell_c)^2
0.13

Jurin's law here assumes equilibrium in a circular vertical tube and neglects contamination, dynamic contact-angle hysteresis, evaporation, detailed meniscus-volume corrections, and finite-reservoir effects.

Newtonian Couette flow

Plate gap, HH
5.0 mm
Shear rate, du/dy=U/Hdu/dy=U/H
100 s⁻¹
Shear stress, τ=μU/H\tau=\mu U/H
0.100 Pa
Plane-Couette ReC=ρ(U/2)(H/2)/μRe_C=\rho(U/2)(H/2)/\mu
623

Transition caution: ReCRe_C is at or above the experimentally observed sustained-turbulence onset of about 360 ± 10 for plane Couette flow. The displayed straight-line profile and τ=μU/H\tau=\mu U/H remain the laminar solution, but a sufficiently disturbed physical flow may not remain laminar.

The relation assumes steady, laminar, isothermal flow of a Newtonian fluid, no slip at both plates, negligible pressure gradient, and a uniform 5 mm gap. The Reynolds-number convention uses half the wall-speed difference and half the plate gap.

Density
998 kg/m³
Specific weight
9.79 kN/m³
Dynamic viscosity
0.001002 Pa·s
Kinematic viscosity
1.00e-6 m²/s
Surface tension
0.0728 N/m
Contact angle
0° assumed

Surface Tension, σ\sigma

Surface tension is the tangential interfacial force per unit length associated with molecular cohesion at a fluid interface. It is equivalently surface energy per unit area for a reversible change in interface area.

Young–Laplace Pressure Jump

Relates pressure difference across a curved interface to its principal radii of curvature.

Δp=σ(1R1+1R2)\Delta p = \sigma\left(\frac{1}{R_1}+\frac{1}{R_2}\right)

Variables

SymbolDescriptionUnit
Δp\Delta pPressure on the concave side minus pressure on the convex sidePa
σ\sigmaSurface tensionN/m
R1R_1First principal radius of curvaturem
R2R_2Second principal radius of curvaturem

Droplets, Soap Bubbles, and Cylindrical Jets

For a spherical liquid droplet, R1=R2=RR_1=R_2=R, so a single interface gives Δp=2σ/R\Delta p=2\sigma/R. A soap bubble has two liquid-gas interfaces, so the total pressure jump is 4σ/R4\sigma/R when both interfaces have nearly the same radius. For a cylindrical liquid jet, one principal radius is RR and the other is effectively infinite, giving Δp=σ/R\Delta p=\sigma/R.

Common Surface-Tension Pressure Jumps

Special cases of the Young–Laplace relation used in elementary hydraulics.

Δpdroplet=2σR,Δpsoap bubble=4σR,Δpjet=σR\Delta p_{\text{droplet}}=\frac{2\sigma}{R}, \qquad \Delta p_{\text{soap bubble}}=\frac{4\sigma}{R}, \qquad \Delta p_{\text{jet}}=\frac{\sigma}{R}

Variables

SymbolDescriptionUnit
RRDroplet, bubble, or jet radiusm
σ\sigmaSurface tensionN/m
Δp\Delta pExcess pressure associated with curvaturePa

Capillary Rise or Depression, hh

Capillary rise or depression is the change in liquid level inside a small tube caused by surface tension and the contact angle between the liquid interface and the solid wall.

Capillary Rise or Depression in a Circular Tube

Balances the vertical surface-tension force with the weight of the displaced liquid column.

h=4σcos⁡θγdh = \frac{4\sigma\cos\theta}{\gamma d}

Variables

SymbolDescriptionUnit
hhSigned capillary height relative to the outside free surfacem
σ\sigmaSurface tensionN/m
θ\thetaContact angle measured through the liquiddegrees or rad
γ\gammaLiquid specific weightN/m3N/m^3
ddInside tube diameterm
Capillary rise and meniscusSurface tension, contact angle, and capillary height.meniscuscontact anglecapillary rise

Capillary rise and meniscus

Surface tension, contact angle, and capillary height.

Capillary Sign Convention

With the contact angle measured through the liquid, θ<90∘\theta<90^\circ gives cos⁡θ>0\cos\theta>0 and a rise, whereas θ>90∘\theta>90^\circ gives cos⁡θ<0\cos\theta<0 and a depression. Use the actual liquid-solid contact angle when it is provided rather than assuming perfect wetting.

Vapor Pressure, pvp_v

Vapor pressure is the saturation pressure of a substance at a specified temperature when its liquid and vapor phases are in equilibrium.

Cavitation Uses Absolute Pressure

Cavitation can begin when the local absolute liquid pressure falls to or below the saturation vapor pressure at the local temperature. A negative gage pressure does not by itself establish cavitation because gage pressure is referenced to the local atmosphere, not to a vacuum.

Bulk Modulus, KK

Bulk modulus is a positive measure of resistance to volumetric compression. It relates an increase in pressure to the corresponding fractional decrease in volume, or equivalently to the fractional increase in density.

Differential Bulk Modulus

Defines local volumetric stiffness for a compressible fluid.

K=−VdpdV=ρdpdρK=-V\frac{dp}{dV}=\rho\frac{dp}{d\rho}

Variables

SymbolDescriptionUnit
KKBulk modulusPa
ppPressurePa
VVFluid volumem3m^3
ρ\rhoFluid densitykg/m3kg/m^3

Small Finite Compression Approximation

Estimates a small volume change when bulk modulus is approximately constant over the pressure interval.

K≈−ΔpΔV/V1K \approx -\frac{\Delta p}{\Delta V/V_1}

Variables

SymbolDescriptionUnit
Δp\Delta pPressure increase over the intervalPa
ΔV\Delta VFinal volume minus initial volumem3m^3
V1V_1Reference initial volumem3m^3

Liquid Compressibility in Engineering Models

Water near ordinary ambient conditions has a bulk modulus of roughly 2.2 GPa2.2\ \text{GPa}, although the value varies with temperature and pressure. Treating a liquid as incompressible is often appropriate for steady-flow calculations, but compressibility becomes important in transients such as water hammer.

Fluid compression and bulk modulusPressure increase associated with a small volume reduction.pressurevolume changebulk modulus

Fluid compression and bulk modulus

Pressure increase associated with a small volume reduction.

Ideal-Gas Equation of State

For an ideal gas, absolute pressure, density, specific gas constant, and absolute temperature are related by the equation of state p=ρRTp=\rho RT.

Ideal-Gas Equation of State

Relates ideal-gas pressure, density, and absolute temperature.

p=ρRTp = \rho R T

Variables

SymbolDescriptionUnit
ppAbsolute gas pressurePa
ρ\rhoGas densitykg/m3kg/m^3
RRSpecific gas constantJ/(kg·K)
TTAbsolute temperatureK

Absolute Quantities in Gas Calculations

Use absolute pressure and absolute temperature in p=ρRTp=\rho RT. For dry air, R≈287 J/(kg⋅K)R\approx287\ \text{J/(kg·K)}. A Celsius temperature or gage pressure cannot be substituted directly into the ideal-gas equation.

Bulk Modulus of an Ideal Gas

For an ideal gas, the effective bulk modulus depends on the compression process. Isothermal compression gives K=pK=p, while a reversible adiabatic (isentropic) process gives K=kpK=kp, where k=cp/cvk=c_p/c_v is the specific-heat ratio. The pressure in these expressions is absolute.

Key Takeaways
  • Density is mass per unit volume; specific weight is density multiplied by local gravitational acceleration; specific volume is the reciprocal of density.
  • Specific gravity is a dimensionless comparison with a stated reference fluid and reference condition.
  • Dynamic viscosity controls Newtonian shear stress, while kinematic viscosity is μ/ρ\mu/\rho and has dimensions of momentum diffusivity.
  • Surface-tension pressure jumps follow interface curvature; droplets, soap bubbles, and cylindrical jets are special cases of the Young–Laplace relation.
  • Capillary rise or depression depends on surface tension, tube diameter, specific weight, and the contact angle measured through the liquid.
  • Vapor-pressure and cavitation checks require absolute pressure at the relevant temperature.
  • Bulk modulus measures volumetric stiffness; finite-difference formulas are approximations over a stated pressure interval.
  • Ideal-gas calculations require absolute pressure and absolute temperature, and gas bulk modulus depends on the thermodynamic process.